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- W2012169852 abstract "Abstract The (Ba 0.95 Ca 0.05 ) 0.8875 Bi 0.075 TiO 3 ceramic composition was prepared using the conventional mixed-oxide technique. X-ray diffraction at room temperature and dielectric permittivity in the temperature range from 85 to 450 K and frequency range from 10 2 to 2 × 10 5 Hz, respectively, were studied. The X-ray spectra were investigated by profile refinement technique with the use of specialized software at room temperature, the (Ba 0.95 Ca 0.05 ) 0.8875 Bi 0.075 TiO 3 composition crystallizes in quadratic perovskite structure. The dielectric measurements show classical ferroelectric behavior. The pyroelectric and piezoelectric results confirm the dielectric measurements. The pyroelectric coefficient is about 69.2 nC/cm 2 K at the transition temperature ( T C = 367 K). The piezoelectric constant is d 31 = 31.1 pC/N and the electromechanical coupling factor is k P = 0.14679. Raman spectra of (Ba 0.95 Ca 0.05 ) 0.8875 Bi 0.075 TiO 3 ceramic were taken at various temperatures and measured over the wave number range from 50 to 1000 cm −1 . All the Raman bands were assigned as the transitional modes of Ba 2+ , Ca 2+ , Bi 3+ and Ti 4+ cations. The temperature evolution of Raman spectra across the transition shows an important evolution characterizing the disorder of the high temperature phase." @default.
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- W2012169852 date "2012-05-01" @default.
- W2012169852 modified "2023-09-25" @default.
- W2012169852 title "X-ray diffraction, dielectric, pyroelectric, piezoelectric and Raman spectroscopy studies on (Ba0.95Ca0.05)0.8875Bi0.075TiO3 ceramic" @default.
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- W2012169852 doi "https://doi.org/10.1016/j.ceramint.2011.12.015" @default.
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