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- W2012170183 abstract "In order to develop novel oligothiophene-based liquid crystals capable of hydrogen bonding, new terthiophene derivatives containing an alkylamide group, N,N′-dialkyl-5,5″-dichloro-2,2′:5′,2″-terthiophene-4,4″-dicarboxamide (DNCnDCl3T, n=8, 18), N,N′-dialkyl-5,5″-dibromo-2,2′:5′,2″-terthiophene-4,4″-dicarboxamide (DNCnDBr3T, n=5, 8, 16, 18), or N,N′-dialkyl-5,5″-diiodo-2,2′:5′,2″-terthiophene-4,4″-dica-rboxamide (DNCnDI3T, n=8, 18), were designed and synthesized, and their thermal behaviour was examined. It was found that DNC18DCl3T, DNC18DI3T and DNCnDBr3T (n=8, 16, 18) form a smectic A phase and that the alkyl chain length greatly affects liquid crystal phase formation. The absence of liquid crystallinity in the corresponding ester derivatives suggests that intermolecular hydrogen bonding also plays a role in the formation of a liquid crystal phases in the DNCnDBr3T system." @default.
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- W2012170183 date "2004-06-01" @default.
- W2012170183 modified "2023-10-18" @default.
- W2012170183 title "Synthesis and liquid crystal properties of a novel family of oligothiophene derivatives" @default.
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- W2012170183 doi "https://doi.org/10.1016/j.tet.2004.04.029" @default.
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