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- W2012173555 abstract "Abstract Photophysical parameters, the rate constants for radiative ( k F ) and nonradiative ( k IC ) for Nile Red (NR) in aprotic polar solvents incapable of hydrogen bonding with NR have been determined. No regular polarity dependence on k IC were observed in contrast to other authors. The effect of temperature on absorption and fluorescence spectra of NR in two selected solvents: ethyl acetate and 1,2-dichloroethane was studied and the electric dipole moment in the excited state S 1 was determined using the Bilot and Kawski theory [L. Bilot, A. Kawski, Z. Naturforsch. 17a (1962) 621, L. Bilot, A. Kawski, Z. Naturforsch. 18a (1963) 10, 256]. For the previously obtained dipole moment in the ground state μ g = 8.2 D [A. Kawski, P. Bojarski, B. Kuklinski, Chem. Phys. Lett. 463 (2008) 410] the change from thermochromic measurements upon excitation of NR is equal to Δ μ = μ e − μ g = 1.75 ± 0.5 D and is in good agreement with the value Δ μ = 1.8 ± 1 D from solvatochromic method. A comparison of the obtained Δ μ value with those of other authors is given and discussed. It has been concluded that the difference between the excited μ e and ground μ g state dipole moments for NR is too small to create a TICT state." @default.
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- W2012173555 date "2009-05-01" @default.
- W2012173555 modified "2023-09-25" @default.
- W2012173555 title "Photophysical properties and thermochromic shifts of electronic spectra of Nile Red in selected solvents. Excited states dipole moments" @default.
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- W2012173555 doi "https://doi.org/10.1016/j.chemphys.2009.03.006" @default.
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