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• W2012173624 abstract "The characterization of the association of an alternating copolymer was performed using theoretical methods (quantum mechanics and molecular mechanics) and experimental methods (cryo-Transmission Electron Microscopy (cryo-TEM), neutron reflectivity and neutron scattering). The most stable conformation obtained for the self-association at pH 7 using theoretical methods is a tubular structure in which eight SMA molecules make one twist of a helix. The tubes can grow in length by continued regular stacking of benzene rings. The nanotubes have inner and outer diameters of about 28 and 41 Å, respectively. The hydrophobic groups are mainly located inside the tube and the hydrophilic groups are mainly on the exterior surface of the tube. They can also associate with themselves creating planes of aligned tubes, which can stack upon each other. The association of alternating copolymers into nanotubes is a novel self-association process. The association of SMA octamers into a tubular structure at pH7 was confirmed experimentally by cryo-TEM and the nanotubes observed were several micrometers long. The shape as well as the inner and outer diameter of the nanotubes were also characterized by neutron scattering and the conformation at the air–water interface by neutron reflectivity." @default.
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• W2012173624 date "2005-02-15" @default.
• W2012173624 modified "2023-09-23" @default.
• W2012173624 title "Characterization of a novel self-association of an alternating copolymer into nanotubes in solution" @default.
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• W2012173624 doi "https://doi.org/10.1080/08927020512331328716" @default.
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