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- W2012179911 abstract "The heat capacities per unit volume and the densities of sodium decanoate (NaDec) in water were measured as a function of concentration and temperature in the range 0.5 to 45 °C. Similar data were obtained for octylamine hydrobromide at 5 and 15 °C. Enthalpies of dilution of NaDec in water were measured at 25 °C. From these and previously published data the apparent and partial molal heat capacities, expansibilities, volumes, and relative enthalpies were determined as a function of temperature and concentration. The concentration dependence of [Formula: see text] and [Formula: see text], is similar to that of other surfactants such as alkyltrimethylammonium bromides and sodium dodecyl sulfate, but in contrast with the other surfactants, [Formula: see text] goes through a sharp maximum in the micellization region at the lower temperatures. These thermodynamic properties can be analysed with a phase-separation model to give the changes in volume, heat capacity, and enthalpy during micellization as a function of temperature. The limitations of this model are also discussed." @default.
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- W2012179911 date "1980-05-15" @default.
- W2012179911 modified "2023-10-17" @default.
- W2012179911 title "Volumetric and thermochemical properties of ionic surfactants: sodium decanoate and octylamine hydrobromide in water" @default.
- W2012179911 doi "https://doi.org/10.1139/v80-152" @default.
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