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- W2012179914 abstract "The ability of the Fluorescence Blob Model (FBM) to probe the chain dynamics of a polymer backbone was verified for the first time by investigating whether it responds to known differences in backbone flexibility for flexible cis-polyisoprene (PIP) and more sterically hindered polystyrene (PS), both randomly labeled with pyrene. For comparable pyrene contents, the steady-state fluorescence spectra indicated that Py-PIP formed considerably more excimer than the Py-PS samples. Analysis of the fluorescence decays with the FBM provided the rate constant for intramolecular excimer formation. This rate constant was much larger for Py-PIP than for Py-PS, in agreement with the enhanced excimer formation observed for Py-PIP. The enhanced ability of Py-PIP to form excimer is attributed to the PIP backbone being less sterically hindered than the PS backbone. This study is the first example of a comparison of the long range polymer chain dynamics for two different polymeric backbones randomly labeled with pyrene." @default.
- W2012179914 created "2016-06-24" @default.
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- W2012179914 creator A5035395541 @default.
- W2012179914 date "2009-11-01" @default.
- W2012179914 modified "2023-09-24" @default.
- W2012179914 title "Comparison of the long range polymer chain dynamics of polystyrene and cis-polyisoprene using polymers randomly labeled with pyrene" @default.
- W2012179914 cites W1516240693 @default.
- W2012179914 cites W1520591873 @default.
- W2012179914 cites W1531640840 @default.
- W2012179914 cites W163354118 @default.
- W2012179914 cites W171268333 @default.
- W2012179914 cites W1964808992 @default.
- W2012179914 cites W1966749100 @default.
- W2012179914 cites W1967334648 @default.
- W2012179914 cites W1967715167 @default.
- W2012179914 cites W1971265368 @default.
- W2012179914 cites W1972740681 @default.
- W2012179914 cites W1975120308 @default.
- W2012179914 cites W1978268468 @default.
- W2012179914 cites W1981217605 @default.
- W2012179914 cites W1982820843 @default.
- W2012179914 cites W1985431370 @default.
- W2012179914 cites W1988852731 @default.
- W2012179914 cites W1992067341 @default.
- W2012179914 cites W1993480843 @default.
- W2012179914 cites W1993923418 @default.
- W2012179914 cites W1994240871 @default.
- W2012179914 cites W1997359855 @default.
- W2012179914 cites W2002620559 @default.
- W2012179914 cites W2004701581 @default.
- W2012179914 cites W2005496147 @default.
- W2012179914 cites W2010321155 @default.
- W2012179914 cites W2011678331 @default.
- W2012179914 cites W2012643870 @default.
- W2012179914 cites W2013795706 @default.
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- W2012179914 cites W2023986840 @default.
- W2012179914 cites W2026205393 @default.
- W2012179914 cites W2026457339 @default.
- W2012179914 cites W2027028837 @default.
- W2012179914 cites W2027304248 @default.
- W2012179914 cites W2029360791 @default.
- W2012179914 cites W2032108902 @default.
- W2012179914 cites W2034735528 @default.
- W2012179914 cites W2036432896 @default.
- W2012179914 cites W2036947147 @default.
- W2012179914 cites W2036977586 @default.
- W2012179914 cites W2041563562 @default.
- W2012179914 cites W2048107516 @default.
- W2012179914 cites W2048236251 @default.
- W2012179914 cites W2055972988 @default.
- W2012179914 cites W2060283154 @default.
- W2012179914 cites W2060416022 @default.
- W2012179914 cites W2064664663 @default.
- W2012179914 cites W2065094990 @default.
- W2012179914 cites W2066241083 @default.
- W2012179914 cites W2067518800 @default.
- W2012179914 cites W2067987181 @default.
- W2012179914 cites W2071587903 @default.
- W2012179914 cites W2072852858 @default.
- W2012179914 cites W2074712224 @default.
- W2012179914 cites W2074859930 @default.
- W2012179914 cites W2082525046 @default.
- W2012179914 cites W2088567564 @default.
- W2012179914 cites W2091658605 @default.
- W2012179914 cites W2091908686 @default.
- W2012179914 cites W2093099939 @default.
- W2012179914 cites W2105004242 @default.
- W2012179914 cites W2108107378 @default.
- W2012179914 cites W2114127353 @default.
- W2012179914 cites W2141856711 @default.
- W2012179914 cites W2143932806 @default.
- W2012179914 cites W2144626203 @default.
- W2012179914 cites W2146814661 @default.
- W2012179914 cites W2171109225 @default.
- W2012179914 cites W2396619354 @default.
- W2012179914 cites W2949649225 @default.
- W2012179914 cites W2951182529 @default.
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- W2012179914 cites W4234386783 @default.
- W2012179914 cites W4236231950 @default.
- W2012179914 cites W4241480019 @default.
- W2012179914 doi "https://doi.org/10.1016/j.polymer.2009.09.036" @default.
- W2012179914 hasPublicationYear "2009" @default.
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