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- W2012181296 abstract "Three new transition metal complexes [Zn(bipyrtds)I2](1), [Cd(bipyrtds)I2] (2) and [Hg(pipdtc)I](3) (where bipyrtds = bipyrrolidine thiuamdisulfide and pipdtc = piperidinecarbodithioate) were prepared by the reaction of the corresponding biscarbodithioates with iodine and were characterized by elemental analysis, IR and NMR spectra. The structures of all the three complexes were determined by single crystal X-ray crystallography. Compounds 1 and 2 contain four coordinated metal atoms and both ZnII and CdII complexes are isostrucutral. Interestingly, complex 3 was found to contain effectively four coordinated mercury atom as a dimer with a relatively long Hg-S (3.084Å) bond. The IR studies are in keeping with the observed thioureide distances. 1H NMR spectra of 1 and 2 show clear differences in environments of α- and β-CH2 protons. However, in 1 a broad signal was observed at 4.02 ppm for α-protons and a multiplet at 2.10 for β-protons. For 2, two triplets appeared at 4.26 and 4.03 ppm for α-protons and two quintets appeared in the range of 2.18 and 2.28 ppm for β-protons. Complex 3 gave three sets of signals. Variation of stereochemical environment with respect to α and β protons of the rings is very clearly observed in the NMR spectra." @default.
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- W2012181296 date "2005-07-01" @default.
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- W2012181296 title "M(S)2(I)2 (M=Zn, Cd) and Hg(S)3I Coordination Environment of Transition Metal Complexes - Synthesis, Spectral, and Single Crystal X-ray Structural Investigations" @default.
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- W2012181296 doi "https://doi.org/10.1002/zaac.200500044" @default.
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