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• W2012183232 abstract "In this paper, we investigate the effects of various potential models in the description of vapor–liquid equilibria (VLE) and adsorption of simple gases on highly graphitized thermal carbon black. It is found that some potential models proposed in the literature are not suitable for the description of VLE (saturated gas and liquid densities and the vapor pressure with temperature). Simple gases, such as neon, argon, krypton, xenon, nitrogen, and methane are studied in this paper. To describe the isotherms on graphitized thermal carbon black correctly, the surface mediation damping factor introduced in our recent publication should be used to calculate correctly the fluid–fluid interaction energy between particles close to the surface. It is found that the damping constant for the noble gases family is linearly dependent on the polarizability, suggesting that the electric field of the graphite surface has a direct induction effect on the induced dipole of these molecules. As a result of this polarization by the graphite surface, the fluid–fluid interaction energy is reduced whenever two particles are near the surface. In the case of methane, we found that the damping constant is less than that of a noble gas having the similar polarizability, while in the case of nitrogen the damping factor is much greater and this could most likely be due to the quadrupolar nature of nitrogen." @default.
• W2012183232 created "2016-06-24" @default.
• W2012183232 creator A5032247361 @default.
• W2012183232 creator A5087318746 @default.
• W2012183232 date "2005-09-01" @default.
• W2012183232 modified "2023-10-08" @default.
• W2012183232 title "Effects of potential models in the vapor–liquid equilibria and adsorption of simple gases on graphitized thermal carbon black" @default.
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• W2012183232 doi "https://doi.org/10.1016/j.fluid.2005.06.012" @default.
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