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- W2012183906 abstract "Nitromethyl, cyanomethyl, and phenylethynyl anions add selectively ortho to arenes containing electron-witdrawing groups and complexed with cyclopentadienyliron. Under similar reaction conditions anions such as alkyl, dichloromethyl and trichloromethyl add in a non-selective way. Addition of the trichloromethyl anion is thermodynamically controlled at extended reaction times and, due to the size of the anion, the meta addition product is favoured. Demetallation of adducts leads to ortho-nitromethylated, cyanomethylated or phenylethynylated arenes, respectively. With symmetrical arene complexes the addition—demetallation sequence leads to the introduction of a trichloromethyl group into the arene ring, yielding a single product. A one-pot procedure for trichloromethylation of dialkylarenes starting from appropriate cyclopentadienyliron complexes gives β-trichloromethylated dialkylarenes in a good yield." @default.
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- W2012183906 date "1991-01-01" @default.
- W2012183906 modified "2023-09-24" @default.
- W2012183906 title "Cyclopentadienyliron-mediated introduction of functionalized alkyl or alkynyl groups to arenes in an addition—demetallation sequence" @default.
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- W2012183906 doi "https://doi.org/10.1016/0022-328x(91)80248-i" @default.
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