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- W2012185936 abstract "The asymmetric unit of the title compound, [Mn(C13H15N4O)2]NO3·CH3OH, contains two independent complex cations, in each of which the Mn(III) ion is located on an inversion centre. The Mn(III) ion is coordinated by four N and two O atoms from two 1,3-bis-{[(1H-pyrrol-2-yl)methyl-idene]amino}-propan-2-olate ligands, resulting in a distorted octa-hedral geometry. The average Mn-ligand bond lengths in the two complex mol-ecules are 2.074 and 2.079 Å. In the crystal, inter-molecular N-H⋯O hydrogen bonds between the pyrrole group of the ligand and the non-coordinating nitrate ion give rise to a chain structure along [10-1]. The methanol solvent mol-ecule and the nitrate ion are connected by an O-H⋯O hydrogen bond." @default.
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- W2012185936 date "2014-09-17" @default.
- W2012185936 modified "2023-09-23" @default.
- W2012185936 title "Crystal structure of bis(1,3-bis{[(1<i>H</i>-pyrrol-2-yl)methylidene]amino-κ<i>N</i>}propan-2-olato-κ<i>O</i>)manganese(III) nitrate methanol monosolvate" @default.
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- W2012185936 doi "https://doi.org/10.1107/s1600536814020406" @default.
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