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• W2012187468 startingPage "139" @default.
• W2012187468 abstract "Different mechanisms of desolvation of ions by thermospray (TSP) vaporization of liquids are critically discussed. It is concluded that field effects cannot play a major role in the desolvation of ions and molecules. This conclusion is supported by results of experiments with dication salts and alkaline-earth metal salts. It was found that at low solute concentrations (⩽10−3 M) single ions and molecules are predominantly desolvated from small droplets by solvent evaporation. The application of a TSP electrolyte at high concentrations of about 0.1 M gives rise to the formation of salt clusters and cluster ions with and without analyte molecules attached, again by solvent evaporation from small droplets. Neutral and ionized molecules and fragments are released from the clusters by volatilization of the salt. The mean diameter of the small droplets is roughly estimated to be less than 10 nm for the applied indirectly heated vaporizer." @default.
• W2012187468 created "2016-06-24" @default.
• W2012187468 creator A5004604096 @default.
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• W2012187468 date "1989-06-01" @default.
• W2012187468 modified "2023-10-16" @default.
• W2012187468 title "Desolvation of ions and molecules in thermospray mass spectrometry" @default.
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• W2012187468 doi "https://doi.org/10.1016/0168-1176(89)85004-9" @default.
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