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- W2012198770 abstract "The uptake of nitric acid on ice, solid sulfuric acid solutions and solid ternary solutions was investigated in a Teflon-coated Knudsen flow reactor at 180–211 K using mass spectrometric detection. The uptake coefficient, γ, decreases from 0.30 at 180 K to 0.06 at 211 K. The Arrhenius representation shows two distinct regimes. The first, at low temperatures (180–190 K), shows a constant uptake coefficient, whereas the second, at high temperatures (>195 K), corresponds to an activation energy Ea = − 7 ± 1 kcal mol−1. At a fixed temperature the uptake coefficient is independent of the concentration of HNO3, thus confirming a rate law first order in [HNO3]. The uptake coefficient of HNO3 on binary H2SO4–H2O solid solutions decreases linearly from 0.20 at 10 wt.% H2SO4 to 0.05 at 98 wt.% H2SO4 at 180 K. At 200 K γ decreases from 0.10 to 0.03 over the same concentration range. The uptake coefficient for the heterogeneous interaction of HNO3 with solid ternary solutions of H2SO4–HNO3–H2O is 0.10 ± 0.03 in the temperature range 185–195 K under conditions where the composition of the interface was held constant using an external flow of H2O. HNO3 uptake on ice fitted a simple Langmuir–Hinshelwood model." @default.
- W2012198770 created "2016-06-24" @default.
- W2012198770 creator A5021054292 @default.
- W2012198770 creator A5064533258 @default.
- W2012198770 date "2001-01-01" @default.
- W2012198770 modified "2023-09-30" @default.
- W2012198770 title "The kinetics of the uptake of HNO3 on ice, solid H2SO4–H2O and solid ternary solutions of H2SO4–HNO3–H2O in the temperature range 180–211 K" @default.
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- W2012198770 doi "https://doi.org/10.1039/b100546o" @default.
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