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- W2012199620 endingPage "2520" @default.
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- W2012199620 abstract "In order to determine the conformation of poly(ethylene oxide) (PEO), 13C satellite spectra of PEO, 1,2-dimethoxyethane (DME), and dioxane were measured at various temperatures in various solvents, and analyzed. Relations between the coupling constants were derived from the linearity between the parameters N = JAB + JA′B and L = JA′B in AA′BB′ spectra of PEO and DME. The vicinal coupling constants for the individual rotational isomers were obtained from the above relations and the temperature dependences of N and L and the enthalpy differences were calculated in each solvent. The gauche rotamer is more stable than the trans isomer by 250–500 cal/mole in all cases examined." @default.
- W2012199620 created "2016-06-24" @default.
- W2012199620 creator A5055963655 @default.
- W2012199620 creator A5059507752 @default.
- W2012199620 date "1974-12-01" @default.
- W2012199620 modified "2023-10-03" @default.
- W2012199620 title "Conformational analysis of poly(ethylene oxide) and model compounds by nuclear magnetic resonance spectroscopy" @default.
- W2012199620 doi "https://doi.org/10.1002/pol.1974.180121210" @default.
- W2012199620 hasPublicationYear "1974" @default.
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