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• W2012201179 abstract "Preparation of solid solution crystals by chemical vapor deposition has been carried out well below the melting temperature. Most of the transition metal monoxides are mutually soluble and are amenable to this process. The composition of the solid solution growth was controlled by the activity of the source components. Solid solutions in the CoO-NiO, wustite, and FeO-MnO systems have been prepared with excellent control of homogeneity, stoichiometry and perfection. The CoO-NiO system is considered in detail. Most compositions showed only isolated dislocations in electron micrographs. One composition, Ni0.66Co0.34O, showed a two phase structure with 200–500 Å particles in the matrix. Electron diffraction studies suggest either an interpenetrating two phase structure or an ordered structure showing super-lattice peaks. Electron micrographs and electron diffraction of oxidized specimens showed a completely different structure. These results suggest an apparent miscibility gap below 800 °C in the NiO-CoO system." @default.
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• W2012201179 date "1972-05-01" @default.
• W2012201179 modified "2023-09-28" @default.
• W2012201179 title "Chemical vapor transport of transition metal oxide solid solutions" @default.
• W2012201179 cites W2020667486 @default.
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• W2012201179 doi "https://doi.org/10.1016/0022-0248(72)90193-5" @default.
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