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- W2012202139 abstract "Abstract The new conjugated cruciform chromophores with donor–acceptor character, 1,4-dithienyl-2,5-bis(diphenylamino-phenyl)benzene ( 2 ) and 1,4-bis((5-(E)-2-(5-octylthiophen-2-yl)vinyl)thiophen-2-yl)-2,5-bis(diphenylamno-phenyl)benzene ( 3 ), were synthesized by Suzuki and Stille coupling reaction, respectively. Compounds 2 and 3 provided with a certain crystal character. In addition, compound 2 showed bright green emission in both CH 2 Cl 2 solution and solid film. However, compound 3 showed green emission in CH 2 Cl 2 solution and orange emission in solid film, which was attributed to the intermolecular interaction. The cyclic voltammetry (CV) and density functional theory (DFT) researches indicated that the symmetry crossing branches mainly influenced the lowest unoccupied molecular orbital (LUMO) levels. Moreover, DFT investigation indicated that compound 2 possessed the linear charge transfer pathway, and compound 3 may possess three different types of charge transfer pathways in excited state." @default.
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- W2012202139 date "2014-11-01" @default.
- W2012202139 modified "2023-09-26" @default.
- W2012202139 title "New conjugated cruciform chromophores with D-π-A structure: Synthesis, characterization and theoretical calculation" @default.
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- W2012202139 doi "https://doi.org/10.1016/j.molstruc.2014.07.066" @default.
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