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- W2012205677 abstract "This is a simple method for the trans-hydroalumination-alkylation of propargylic alcohols, giving stereochemically defined trisubstituted allylic alcohols. This method complements the known procedure for the cis-hydroalumination-alkylation of allylic alcohols with DIBAL-H. The method uses inexpensive and relatively safe Vitride (Red-Al) as the hydroalumination agent. The method is not sensitive to the steric hindrance in the allylic alcohol. Only reactive electrophiles like allylic, benzylic and propargylic halides afford good yields of products." @default.
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- W2012205677 date "2006-11-01" @default.
- W2012205677 modified "2023-10-18" @default.
- W2012205677 title "trans-Hydroalumination-Alkylation of Propargylic Alcohols" @default.
- W2012205677 doi "https://doi.org/10.1055/s-2006-949482" @default.
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