Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012207958> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W2012207958 abstract "The matrix isolation technique has been combined with theoretical calculations to identify and characterize the photoproducts in the reaction of PH3 with OVCl3 and CrCl2O2. In contrast to previous studies, HCl elimination from an initial complex is not observed. Instead, a number of product bands, some quite intense, were observed and have been assigned to phosphine oxide, H3PO, through the direct O atom transfer from the transition metal oxo compound. This identification was supported by extensive isotopic labeling, and by comparison to theoretical calculations. H3PO formed in this manner is cage-paired and interacts with the transition metal fragment (VCl3 or Cl2CrO), leading to a 113 cm-1 red-shift of the PO stretching mode relative to isolated monomeric H3PO." @default.
- W2012207958 created "2016-06-24" @default.
- W2012207958 creator A5044377317 @default.
- W2012207958 creator A5065321272 @default.
- W2012207958 date "2003-11-18" @default.
- W2012207958 modified "2023-09-27" @default.
- W2012207958 title "Matrix Isolation and Theoretical Study of the Photochemical Reaction of PH3 with OVCl3 and CrCl2O2." @default.
- W2012207958 cites W2952482725 @default.
- W2012207958 doi "https://doi.org/10.1002/chin.200346020" @default.
- W2012207958 hasPublicationYear "2003" @default.
- W2012207958 type Work @default.
- W2012207958 sameAs 2012207958 @default.
- W2012207958 citedByCount "0" @default.
- W2012207958 crossrefType "journal-article" @default.
- W2012207958 hasAuthorship W2012207958A5044377317 @default.
- W2012207958 hasAuthorship W2012207958A5065321272 @default.
- W2012207958 hasConcept C106487976 @default.
- W2012207958 hasConcept C106773901 @default.
- W2012207958 hasConcept C147597530 @default.
- W2012207958 hasConcept C149635348 @default.
- W2012207958 hasConcept C161790260 @default.
- W2012207958 hasConcept C178790620 @default.
- W2012207958 hasConcept C185592680 @default.
- W2012207958 hasConcept C2777716191 @default.
- W2012207958 hasConcept C2777896788 @default.
- W2012207958 hasConcept C2779851234 @default.
- W2012207958 hasConcept C2781082197 @default.
- W2012207958 hasConcept C32909587 @default.
- W2012207958 hasConcept C41008148 @default.
- W2012207958 hasConcept C43617362 @default.
- W2012207958 hasConcept C544153396 @default.
- W2012207958 hasConcept C58312451 @default.
- W2012207958 hasConcept C75473681 @default.
- W2012207958 hasConceptScore W2012207958C106487976 @default.
- W2012207958 hasConceptScore W2012207958C106773901 @default.
- W2012207958 hasConceptScore W2012207958C147597530 @default.
- W2012207958 hasConceptScore W2012207958C149635348 @default.
- W2012207958 hasConceptScore W2012207958C161790260 @default.
- W2012207958 hasConceptScore W2012207958C178790620 @default.
- W2012207958 hasConceptScore W2012207958C185592680 @default.
- W2012207958 hasConceptScore W2012207958C2777716191 @default.
- W2012207958 hasConceptScore W2012207958C2777896788 @default.
- W2012207958 hasConceptScore W2012207958C2779851234 @default.
- W2012207958 hasConceptScore W2012207958C2781082197 @default.
- W2012207958 hasConceptScore W2012207958C32909587 @default.
- W2012207958 hasConceptScore W2012207958C41008148 @default.
- W2012207958 hasConceptScore W2012207958C43617362 @default.
- W2012207958 hasConceptScore W2012207958C544153396 @default.
- W2012207958 hasConceptScore W2012207958C58312451 @default.
- W2012207958 hasConceptScore W2012207958C75473681 @default.
- W2012207958 hasLocation W20122079581 @default.
- W2012207958 hasOpenAccess W2012207958 @default.
- W2012207958 hasPrimaryLocation W20122079581 @default.
- W2012207958 hasRelatedWork W1620847507 @default.
- W2012207958 hasRelatedWork W1985439595 @default.
- W2012207958 hasRelatedWork W2041711168 @default.
- W2012207958 hasRelatedWork W2083387355 @default.
- W2012207958 hasRelatedWork W2162175307 @default.
- W2012207958 hasRelatedWork W2314092572 @default.
- W2012207958 hasRelatedWork W2342842973 @default.
- W2012207958 hasRelatedWork W2950422491 @default.
- W2012207958 hasRelatedWork W2999061818 @default.
- W2012207958 hasRelatedWork W3004475341 @default.
- W2012207958 isParatext "false" @default.
- W2012207958 isRetracted "false" @default.
- W2012207958 magId "2012207958" @default.
- W2012207958 workType "article" @default.