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- W2012214741 abstract "Abstract The addition of aromatic compounds to the double bond of oleic acid was studied using solid acid catalysts. For example, in the presence of an acid clay catalyst (bentonite), phenol reacted with oleic acid to yield 96% of an alkylphenol addition product. When toluene was used as the aromatic reactant, however, the yield of alkylbenzene addition product was less than 2%. In this instance, the major reactions observed were elaidinization and migration of the double bond of oleic acid. The addition of phenol to oleic acid in greater than 95% yield also was accomplished with the use of a sulfonic acid ion‐exchange resin catalyst. This same catalyst also catalyzed the addition of toluene and benzene to oleic acid to yield 82% and 22%, respectively, of alkylbenzene‐type addition products. In the latter instances, the major side product formed was γ‐stearolactone. Capillary gas chromatographic (GC) analyses of the alkylbenzene addition products obtained showed them to be mixtures of positional isomers. The isomer distributions were subsequently determined by GC‐mass spectrometry (MS)." @default.
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- W2012214741 date "1984-06-01" @default.
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- W2012214741 title "Addition of aromatic compounds to oleic acid catalyzed by heterogeneous acid catalysts" @default.
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- W2012214741 doi "https://doi.org/10.1007/bf02636216" @default.
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