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- W2012220171 abstract "To investigate the intramolecular 1,5-type C-···Si interaction, (2-(trimethylsilyl)phenyl)phosphonium methylides 1 were prepared. Treatment of the precursors, the methyl(2-(trimethylsilyl)phenyl)phosphonium iodides 2 (R = Ph, Me), with sodium hexamethyldisilazide in THF afforded the phosphonium methylides 1, which readily underwent anionic 1,4-silyl migration to form the silylated ylides 4 at low temperatures. They were characterized by NMR and trapping experiments." @default.
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- W2012220171 date "2006-03-23" @default.
- W2012220171 modified "2023-10-14" @default.
- W2012220171 title "Anionic 1,4-Silyl Migration in (2-(Trimethylsilyl)phenyl)phosphonium Methylides" @default.
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- W2012220171 doi "https://doi.org/10.1021/om051080o" @default.
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