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• W2012247949 abstract "Starting from D-seco derivatives of 5-androstene 1-3, the D-homo lactones, 4 and 5, were synthesized. By the Oppenauer oxidation and/or by dehydration of 4 and 5 with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) or 2,3,5,6-tetrachloro-1,4-benzoquinone (chloranil), the corresponding D-lactones 6-12 were obtained. The structures of 6 and 10 were unambiguously proved by the appropriate X-ray structural analysis. Anti-aromatase assay showed that tested compounds possess inhibition potency, however, two to four times smaller (IC50 from 0.2 to 0.7 microM, respectively) in comparison to aminoglutethimide (AG)." @default.
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• W2012247949 date "2005-01-01" @default.
• W2012247949 modified "2023-10-16" @default.
• W2012247949 title "Synthesis and anti-aromatase activity of some new steroidal D-lactones" @default.
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• W2012247949 doi "https://doi.org/10.1016/j.steroids.2004.10.005" @default.
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