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• W2012252598 endingPage "1345" @default.
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• W2012252598 abstract "Base-catalyzed condensation of diferrocenylsilanediol, Fc2Si(OH)2 (3; Fc = (η-C5H4)Fe(η-C5H5)), in refluxing 95% ethanol (ca. 90 °C) affords a novel cyclotrisiloxane with six ferrocenyl substituents, [Fc2SiO]3 (4), in 74% yield. At 60 °C, the intermediate tetraferrocenyldisiloxanediol, [HOSiFc2]2O (5), could be isolated in 78% yield. NMR, IR, Raman, and UV−vis data for 4 and 5 were consistent with the proposed structures. Electrochemical studies of 4 showed that there are substantial interactions between the ferrocenyl groups attached to the same Si atom and weaker interactions between the ferrocenyl groups attached to adjacent Si atoms. Furthermore, single-crystal X-ray diffraction studies of these compounds revealed an essentially planar Si3O3 ring in 4 and a novel hydrogen-bonded chain motif for disiloxanediol 5. Surprisingly, 4 and 5 cocrystallize in a 1:3 ratio from a CH2Cl2/hexanes mixture to afford an interesting helical hydrogen-bonding structure for the siloxanediol 5." @default.
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• W2012252598 date "1999-03-01" @default.
• W2012252598 modified "2023-10-07" @default.
• W2012252598 title "Ferrocenylsiloxane Chemistry: Synthesis and Characterization of Hexaferrocenylcyclotrisiloxane and Tetraferrocenyldisiloxanediol" @default.
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• W2012252598 doi "https://doi.org/10.1021/om9809567" @default.
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