FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012254471> ?p ?o ?g. }

• W2012254471 endingPage "85" @default.
• W2012254471 startingPage "78" @default.
• W2012254471 abstract "MFI-type zeolites were characterized using powder X-ray diffraction (XRD), and positron annihilation lifetime spectroscopy (PALS) to uncover the hierarchical porous properties with Si/Al ratios varying from 30 to >1000 (high silica MFI). Structural dynamics were observed in response to exposure of the zeolites to seawater solutions, mimicking service conditions for use in membrane desalination or other ionic solution applications (e.g. sensors). PALS results indicated MFI channels between 0.27 and 0.36 nm. All materials had microporous grain boundaries of 1.1 nm. Mesopores were also detected at approximately 8 nm in size for all materials. However the volume of microporous grain boundaries reduced with increasing alumina as explained by increasing presence of cations. Seawater exposure had a strong and complex effect on all materials. Initially widely variable crystal dimensions were stabilized by seawater exposure. The highest alumina content ZSM-5 (Si/Al = 30) demonstrated net exchange, replacing K+ from synthesis impurities with Na+ leading to little overall change in porous features. Higher silica materials, including high silica MFI, demonstrated an overall release of ions, principally Na+ and K+, which were liberated mainly from the zeolite channels, yet these materials adsorbed Ca2+ in the microporous grain boundaries and Mg2+ in the mesoporous grain boundaries. Si/Al = 100 appeared to be a unique ratio, allowing the material to possess the same Na+ adsorption features (and hydrophilicity) of high alumina materials, but ion interactions resembling high silica materials. MFI-type zeolite is therefore shown to be highly configurable using Si/Al ratio for a wide variety of applications in the presence of ions." @default.
• W2012254471 created "2016-06-24" @default.
• W2012254471 creator A5000363798 @default.
• W2012254471 creator A5001857687 @default.
• W2012254471 creator A5006317445 @default.
• W2012254471 creator A5009655352 @default.
• W2012254471 creator A5018928264 @default.
• W2012254471 creator A5046639988 @default.
• W2012254471 creator A5062458918 @default.
• W2012254471 date "2013-06-01" @default.
• W2012254471 modified "2023-10-16" @default.
• W2012254471 title "Designing hierarchical porous features of ZSM-5 zeolites via Si/Al ratio and their dynamic behavior in seawater ion complexes" @default.
• W2012254471 cites W128252969 @default.
• W2012254471 cites W1964280047 @default.
• W2012254471 cites W1964365356 @default.
• W2012254471 cites W1970527948 @default.
• W2012254471 cites W1973204812 @default.
• W2012254471 cites W1974608911 @default.
• W2012254471 cites W1979801322 @default.
• W2012254471 cites W1980145065 @default.
• W2012254471 cites W1991798784 @default.
• W2012254471 cites W1995396692 @default.
• W2012254471 cites W1997037574 @default.
• W2012254471 cites W2000182116 @default.
• W2012254471 cites W2002896524 @default.
• W2012254471 cites W2014900473 @default.
• W2012254471 cites W2025846142 @default.
• W2012254471 cites W2037225132 @default.
• W2012254471 cites W2040401840 @default.
• W2012254471 cites W2042733175 @default.
• W2012254471 cites W2046737547 @default.
• W2012254471 cites W2049362515 @default.
• W2012254471 cites W2049566461 @default.
• W2012254471 cites W2055794534 @default.
• W2012254471 cites W2056057651 @default.
• W2012254471 cites W2064404394 @default.
• W2012254471 cites W2070627620 @default.
• W2012254471 cites W2074688963 @default.
• W2012254471 cites W2076051855 @default.
• W2012254471 cites W2079600712 @default.
• W2012254471 cites W2079703285 @default.
• W2012254471 cites W2082409196 @default.
• W2012254471 cites W2082872125 @default.
• W2012254471 cites W2083642264 @default.
• W2012254471 cites W2083720209 @default.
• W2012254471 cites W2088230634 @default.
• W2012254471 cites W2088398969 @default.
• W2012254471 cites W2088523430 @default.
• W2012254471 cites W2093609044 @default.
• W2012254471 cites W2098183862 @default.
• W2012254471 cites W2108343501 @default.
• W2012254471 cites W2127330764 @default.
• W2012254471 cites W2147635736 @default.
• W2012254471 cites W2170126783 @default.
• W2012254471 doi "https://doi.org/10.1016/j.micromeso.2013.02.005" @default.
• W2012254471 hasPublicationYear "2013" @default.
• W2012254471 type Work @default.
• W2012254471 sameAs 2012254471 @default.
• W2012254471 citedByCount "25" @default.
• W2012254471 countsByYear W20122544712013 @default.
• W2012254471 countsByYear W20122544712014 @default.
• W2012254471 countsByYear W20122544712015 @default.
• W2012254471 countsByYear W20122544712016 @default.
• W2012254471 countsByYear W20122544712017 @default.
• W2012254471 countsByYear W20122544712018 @default.
• W2012254471 countsByYear W20122544712020 @default.
• W2012254471 countsByYear W20122544712023 @default.
• W2012254471 crossrefType "journal-article" @default.
• W2012254471 hasAuthorship W2012254471A5000363798 @default.
• W2012254471 hasAuthorship W2012254471A5001857687 @default.
• W2012254471 hasAuthorship W2012254471A5006317445 @default.
• W2012254471 hasAuthorship W2012254471A5009655352 @default.
• W2012254471 hasAuthorship W2012254471A5018928264 @default.
• W2012254471 hasAuthorship W2012254471A5046639988 @default.
• W2012254471 hasAuthorship W2012254471A5062458918 @default.
• W2012254471 hasBestOaLocation W20122544712 @default.
• W2012254471 hasConcept C111368507 @default.
• W2012254471 hasConcept C127313418 @default.
• W2012254471 hasConcept C127413603 @default.
• W2012254471 hasConcept C145148216 @default.
• W2012254471 hasConcept C147789679 @default.
• W2012254471 hasConcept C150394285 @default.
• W2012254471 hasConcept C159985019 @default.
• W2012254471 hasConcept C161790260 @default.
• W2012254471 hasConcept C178790620 @default.
• W2012254471 hasConcept C179104552 @default.
• W2012254471 hasConcept C185592680 @default.
• W2012254471 hasConcept C191897082 @default.
• W2012254471 hasConcept C192562407 @default.
• W2012254471 hasConcept C197248824 @default.
• W2012254471 hasConcept C2182769 @default.
• W2012254471 hasConcept C2777496208 @default.
• W2012254471 hasConcept C2778077586 @default.
• W2012254471 hasConcept C42360764 @default.
• W2012254471 hasConcept C47908070 @default.
• W2012254471 hasConcept C6648577 @default.
• W2012254471 hasConcept C82776694 @default.
• W2012254471 hasConcept C85704489 @default.

• next