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- W2012258766 abstract "Abstract The reaction of Co(CN)5OH22− with Se(IV) oxide in aqueous solution has been studied between pH 2 and 12 at 25°C and μ = 1.00 M (NaClO4). The reaction was found to be pseudo-first order in Co(CN)5OH2−2 with k obs = (47.0±1.5) [HSeO 3 − ] {1 + (2.45 ± 0.17)10 6 [H + ]} sec −1 . The rate law was interpreted to mean tha [HSeO3−] was the reacting species and the proton dependence arose from the acid-base properties of an intermediate. The unusually large rate constant for anation was attributed to electrophilic attack of HSeO3− on the aquo oxygen of the Co(CN)5OH2−2." @default.
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- W2012258766 date "1978-01-01" @default.
- W2012258766 modified "2023-09-26" @default.
- W2012258766 title "Anation of pentacyanoaquocobaltate(III) by selenium(IV) oxide" @default.
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- W2012258766 doi "https://doi.org/10.1016/0022-1902(78)80517-x" @default.
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