Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012302340> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2012302340 abstract "Rate constants have been determined in different solvents for hydrogen atom abstraction from alkyl-substituted phenols and deuteriated analogues by polyvinyl acetate radical (R˙). The following solvents were used: ethyl acetate, ethyl [2H3]acetate, ethyl pivalate, ethyl trifluoroacetate, acetone, [2H6]acetone, dimethyl sulphoxide. The reactivity of the phenols and the primary kinetic deuterium isotope effect (p.k.i.e.) demonstrate a strong solvent dependence exhibiting the highest values in ethyl trifluoroacetate (p.k.i.e. 57 ± 23 for 2,4,6-trimethylphenol at 50 °C). Incorporation of CH314COOCH2CH3 and (CH3)3C14COOCH2CH3 into polyvinyl acetate increases in the presence of phenols. These facts conclusively prove that hydrogen atom abstraction proceeds within the hydrogen bond to the radical formed by addition of R˙ to the ester carbonyl hydrogen bonded to phenol." @default.
- W2012302340 created "2016-06-24" @default.
- W2012302340 creator A5012638866 @default.
- W2012302340 creator A5032446294 @default.
- W2012302340 creator A5045373730 @default.
- W2012302340 creator A5077988654 @default.
- W2012302340 creator A5088624182 @default.
- W2012302340 date "1978-01-01" @default.
- W2012302340 modified "2023-09-23" @default.
- W2012302340 title "The mechanism of hydrogen atom abstraction from phenols involved in hydrogen bonding with ester carbonyl groups" @default.
- W2012302340 doi "https://doi.org/10.1039/p29780000405" @default.
- W2012302340 hasPublicationYear "1978" @default.
- W2012302340 type Work @default.
- W2012302340 sameAs 2012302340 @default.
- W2012302340 citedByCount "3" @default.
- W2012302340 crossrefType "journal-article" @default.
- W2012302340 hasAuthorship W2012302340A5012638866 @default.
- W2012302340 hasAuthorship W2012302340A5032446294 @default.
- W2012302340 hasAuthorship W2012302340A5045373730 @default.
- W2012302340 hasAuthorship W2012302340A5077988654 @default.
- W2012302340 hasAuthorship W2012302340A5088624182 @default.
- W2012302340 hasConcept C112887158 @default.
- W2012302340 hasConcept C121332964 @default.
- W2012302340 hasConcept C142724271 @default.
- W2012302340 hasConcept C155647269 @default.
- W2012302340 hasConcept C178790620 @default.
- W2012302340 hasConcept C185592680 @default.
- W2012302340 hasConcept C204787440 @default.
- W2012302340 hasConcept C2776640939 @default.
- W2012302340 hasConcept C2776910235 @default.
- W2012302340 hasConcept C2777702071 @default.
- W2012302340 hasConcept C2777728882 @default.
- W2012302340 hasConcept C2779858419 @default.
- W2012302340 hasConcept C2780263894 @default.
- W2012302340 hasConcept C2780471494 @default.
- W2012302340 hasConcept C2781213060 @default.
- W2012302340 hasConcept C32909587 @default.
- W2012302340 hasConcept C512968161 @default.
- W2012302340 hasConcept C58364064 @default.
- W2012302340 hasConcept C62520636 @default.
- W2012302340 hasConcept C69928629 @default.
- W2012302340 hasConcept C71924100 @default.
- W2012302340 hasConcept C75473681 @default.
- W2012302340 hasConcept C81022585 @default.
- W2012302340 hasConceptScore W2012302340C112887158 @default.
- W2012302340 hasConceptScore W2012302340C121332964 @default.
- W2012302340 hasConceptScore W2012302340C142724271 @default.
- W2012302340 hasConceptScore W2012302340C155647269 @default.
- W2012302340 hasConceptScore W2012302340C178790620 @default.
- W2012302340 hasConceptScore W2012302340C185592680 @default.
- W2012302340 hasConceptScore W2012302340C204787440 @default.
- W2012302340 hasConceptScore W2012302340C2776640939 @default.
- W2012302340 hasConceptScore W2012302340C2776910235 @default.
- W2012302340 hasConceptScore W2012302340C2777702071 @default.
- W2012302340 hasConceptScore W2012302340C2777728882 @default.
- W2012302340 hasConceptScore W2012302340C2779858419 @default.
- W2012302340 hasConceptScore W2012302340C2780263894 @default.
- W2012302340 hasConceptScore W2012302340C2780471494 @default.
- W2012302340 hasConceptScore W2012302340C2781213060 @default.
- W2012302340 hasConceptScore W2012302340C32909587 @default.
- W2012302340 hasConceptScore W2012302340C512968161 @default.
- W2012302340 hasConceptScore W2012302340C58364064 @default.
- W2012302340 hasConceptScore W2012302340C62520636 @default.
- W2012302340 hasConceptScore W2012302340C69928629 @default.
- W2012302340 hasConceptScore W2012302340C71924100 @default.
- W2012302340 hasConceptScore W2012302340C75473681 @default.
- W2012302340 hasConceptScore W2012302340C81022585 @default.
- W2012302340 hasLocation W20123023401 @default.
- W2012302340 hasOpenAccess W2012302340 @default.
- W2012302340 hasPrimaryLocation W20123023401 @default.
- W2012302340 hasRelatedWork W1487564609 @default.
- W2012302340 hasRelatedWork W1569070162 @default.
- W2012302340 hasRelatedWork W1978639197 @default.
- W2012302340 hasRelatedWork W1979949985 @default.
- W2012302340 hasRelatedWork W1981393601 @default.
- W2012302340 hasRelatedWork W1983533472 @default.
- W2012302340 hasRelatedWork W1984291908 @default.
- W2012302340 hasRelatedWork W1995166979 @default.
- W2012302340 hasRelatedWork W1995463757 @default.
- W2012302340 hasRelatedWork W1996895409 @default.
- W2012302340 hasRelatedWork W1998861404 @default.
- W2012302340 hasRelatedWork W2030071444 @default.
- W2012302340 hasRelatedWork W2035594091 @default.
- W2012302340 hasRelatedWork W2047030188 @default.
- W2012302340 hasRelatedWork W2049077021 @default.
- W2012302340 hasRelatedWork W2080186039 @default.
- W2012302340 hasRelatedWork W2088768022 @default.
- W2012302340 hasRelatedWork W2333931864 @default.
- W2012302340 hasRelatedWork W2949207807 @default.
- W2012302340 hasRelatedWork W2949858495 @default.
- W2012302340 isParatext "false" @default.
- W2012302340 isRetracted "false" @default.
- W2012302340 magId "2012302340" @default.
- W2012302340 workType "article" @default.