FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012305501> ?p ?o ?g. }

• W2012305501 endingPage "1837" @default.
• W2012305501 startingPage "1829" @default.
• W2012305501 abstract "Finely well-defined polystyrene nanocomposites were prepared by ATRP method in bulk at 110°C using organically modified montemorillonite, cloisite 30B. The living nature of ATRP reaction was employed to in situ synthesize tailor-made polystyrene nanocomposite with narrow molecular weight distribution and controlled molecular weight polystyrene chains. The amount of clay loading and time of swelling of clay in the monomer before polymerization were proved to have a positive effect on polymerization rate and also broadened the molecular weight destribution. The gas chromatography (GC) results showed the linear increase of Ln(M0/M) versus time, which indicates the controlled/living polymerization in the presence of nanoclay. Another confirmation of the living nature of the polymerization was linear elevation of molecular weight against monomer conversion concluded from gel permeation chromatography (GPC) data. X-ray diffraction analysis showed the interlayer spacing of nanoclay platelets as well as the exfoliated clay morphology in the nanocomposite samples. Transfer electron microscopy (TEM) revealed the exfoliated morphology of the in situ prepared nanocomposite as opposed to conventional solution-blending technique which resulted in an intercalated structure. The effect of nanoclay on acceleration of polymerization was proved by GC and GPC; similarly, Fourier transform infrared spectroscopy (FTIR) was used to discuss the reasons of such a rate acceleration. A shifting in the wave number of characteristic bonds of nanoclay after polymerization mostly in the case of OH and SiO bonds, revealed the interaction between polymer chains and clay layers which resulted in an accelerated polymerization process. The living nature of polymeric chains was more elucidated by FTIR data. Atomic force microscopy (AFM) images also confirmed the proper dispersion of nanoparticles in the polymer medium. POLYM. COMPOS., 31:1829–1837, 2010. © 2010 Society of Plastics Engineers" @default.
• W2012305501 created "2016-06-24" @default.
• W2012305501 creator A5024198459 @default.
• W2012305501 creator A5039060293 @default.
• W2012305501 creator A5079020789 @default.
• W2012305501 creator A5089364014 @default.
• W2012305501 date "2010-02-16" @default.
• W2012305501 modified "2023-10-10" @default.
• W2012305501 title "Synthesis and characterization of clay dispersed polystyrene nanocomposite via atom transfer radical polymerization" @default.
• W2012305501 cites W1966863664 @default.
• W2012305501 cites W1977343932 @default.
• W2012305501 cites W1979189651 @default.
• W2012305501 cites W1986695961 @default.
• W2012305501 cites W1988776964 @default.
• W2012305501 cites W1991893818 @default.
• W2012305501 cites W2002064117 @default.
• W2012305501 cites W2004015845 @default.
• W2012305501 cites W2018087879 @default.
• W2012305501 cites W2020371995 @default.
• W2012305501 cites W2028173148 @default.
• W2012305501 cites W2029327466 @default.
• W2012305501 cites W2033684187 @default.
• W2012305501 cites W2037786714 @default.
• W2012305501 cites W2041300273 @default.
• W2012305501 cites W2048812423 @default.
• W2012305501 cites W2055393399 @default.
• W2012305501 cites W2055927042 @default.
• W2012305501 cites W2070257266 @default.
• W2012305501 cites W2071240566 @default.
• W2012305501 cites W2077904702 @default.
• W2012305501 cites W2078856433 @default.
• W2012305501 cites W2079335509 @default.
• W2012305501 cites W2081361953 @default.
• W2012305501 cites W2081962413 @default.
• W2012305501 cites W2091665035 @default.
• W2012305501 cites W2095061167 @default.
• W2012305501 cites W2095066235 @default.
• W2012305501 cites W2098264850 @default.
• W2012305501 cites W2114474703 @default.
• W2012305501 cites W2150184000 @default.
• W2012305501 cites W2151671463 @default.
• W2012305501 cites W2161610462 @default.
• W2012305501 cites W242198376 @default.
• W2012305501 cites W4244443937 @default.
• W2012305501 doi "https://doi.org/10.1002/pc.20975" @default.
• W2012305501 hasPublicationYear "2010" @default.
• W2012305501 type Work @default.
• W2012305501 sameAs 2012305501 @default.
• W2012305501 citedByCount "47" @default.
• W2012305501 countsByYear W20123055012012 @default.
• W2012305501 countsByYear W20123055012013 @default.
• W2012305501 countsByYear W20123055012014 @default.
• W2012305501 countsByYear W20123055012015 @default.
• W2012305501 countsByYear W20123055012016 @default.
• W2012305501 countsByYear W20123055012017 @default.
• W2012305501 countsByYear W20123055012018 @default.
• W2012305501 countsByYear W20123055012019 @default.
• W2012305501 countsByYear W20123055012020 @default.
• W2012305501 countsByYear W20123055012021 @default.
• W2012305501 countsByYear W20123055012022 @default.
• W2012305501 crossrefType "journal-article" @default.
• W2012305501 hasAuthorship W2012305501A5024198459 @default.
• W2012305501 hasAuthorship W2012305501A5039060293 @default.
• W2012305501 hasAuthorship W2012305501A5079020789 @default.
• W2012305501 hasAuthorship W2012305501A5089364014 @default.
• W2012305501 hasConcept C111998727 @default.
• W2012305501 hasConcept C127413603 @default.
• W2012305501 hasConcept C150539798 @default.
• W2012305501 hasConcept C158117686 @default.
• W2012305501 hasConcept C159985019 @default.
• W2012305501 hasConcept C160892712 @default.
• W2012305501 hasConcept C166940927 @default.
• W2012305501 hasConcept C188027245 @default.
• W2012305501 hasConcept C192562407 @default.
• W2012305501 hasConcept C2777922577 @default.
• W2012305501 hasConcept C42360764 @default.
• W2012305501 hasConcept C44228677 @default.
• W2012305501 hasConcept C521977710 @default.
• W2012305501 hasConcept C63179538 @default.
• W2012305501 hasConcept C92880739 @default.
• W2012305501 hasConceptScore W2012305501C111998727 @default.
• W2012305501 hasConceptScore W2012305501C127413603 @default.
• W2012305501 hasConceptScore W2012305501C150539798 @default.
• W2012305501 hasConceptScore W2012305501C158117686 @default.
• W2012305501 hasConceptScore W2012305501C159985019 @default.
• W2012305501 hasConceptScore W2012305501C160892712 @default.
• W2012305501 hasConceptScore W2012305501C166940927 @default.
• W2012305501 hasConceptScore W2012305501C188027245 @default.
• W2012305501 hasConceptScore W2012305501C192562407 @default.
• W2012305501 hasConceptScore W2012305501C2777922577 @default.
• W2012305501 hasConceptScore W2012305501C42360764 @default.
• W2012305501 hasConceptScore W2012305501C44228677 @default.
• W2012305501 hasConceptScore W2012305501C521977710 @default.
• W2012305501 hasConceptScore W2012305501C63179538 @default.
• W2012305501 hasConceptScore W2012305501C92880739 @default.
• W2012305501 hasIssue "11" @default.
• W2012305501 hasLocation W20123055011 @default.
• W2012305501 hasOpenAccess W2012305501 @default.

• next