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- W2012306670 abstract "The ligand-exchange kinetics between the enantiomers of [Cu(alamp)] or[Cu(promp)] and (S)-pdta are measured by CD spectroscopy; threedifferent reaction intermediates are proposed, involving the threedifferent states of N-protonation of pdta; at pH < 7 an associativemechanism involving a cage-like, hydrogen-bonded intermediate is suggestedfor [Cu(alamp)] in which the metal ion is transferred in a single ratelimiting step from one ligand to the other." @default.
- W2012306670 created "2016-06-24" @default.
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- W2012306670 date "1997-01-01" @default.
- W2012306670 modified "2023-09-26" @default.
- W2012306670 title "Stereoselectivity and mechanism of Cu2+ transfer between chiral, multidentate ligands" @default.
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- W2012306670 doi "https://doi.org/10.1039/a701832k" @default.
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