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- W2012307726 abstract "Complex formation between N-phenylmaleimide and cyclohexylvinylketone was studied by the proton magnetic resonance method (PMR), and the complex equilibrium constant was determined: Ke = 0.021 1./mole. It was found that by radical copolymerization of the studied monomers, copolymers of equimolar composition are formed. The copolymerization constants both of the free and of the complex-bound monomers were determined: r1≌0, r2 = 0·08, r2c = 0·005, r2c1 = 0·009. By the “shift of rate maximum” kinetic method, participation of donor-acceptor complexes in the chain-growth reaction could be quantitatively determined (α = k12/k21 = 1·84, β1 = k1c/k12 = 22·01 and β = k2c/k21 = 4·75), and the statistical parameters of the N-phenylmaleimide-cyclohexylvinylketone copolymerization could be characterized." @default.
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- W2012307726 date "1986-01-01" @default.
- W2012307726 modified "2023-09-27" @default.
- W2012307726 title "Alternating copolymerization of N-phenylmaleimide with cyclohexylvinylketone" @default.
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- W2012307726 doi "https://doi.org/10.1016/0032-3950(86)90166-8" @default.
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