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- W2012317215 abstract "Abstract Four platinum(II) complexes, [PtCl2L] (L = (4-fluorophenyl)pyridin-2-ylmethylene-amine, 1; (4-chlorophenyl)pyridin-2-ylmethyleneamine, 2; (4-bromophenyl)pyridin-2-ylmethyleneamine, 3 and (4-iodophenyl)pyridin-2-ylmethyleneamine, 4) have been synthesized and characterized by CHN analysis, IR and UV–Vis spectroscopy. The crystal structures of 1 and 2 were determined using single crystal X-ray diffraction. The coordination polyhedron about the platinum (II) center in the complexes is best described as distorted square planar. The complexes undergo stacking to form a zigzag Pt···Pt···Pt chain containing both short (3.57(7) A in 1 and 3.62(8) A in 2) and long (5.16(7) A in 1 and 5.41(9) A in 2) Pt···Pt separations through the crystal. The compounds absorb moderately in the visible region, owing to a charge-transfer-to-diimine electronic transition. The redox potentials are approximately insensitive to the substituents on the phenyl ring of the ligands." @default.
- W2012317215 created "2016-06-24" @default.
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- W2012317215 date "2010-07-01" @default.
- W2012317215 modified "2023-09-25" @default.
- W2012317215 title "Platinum(II) complexes with bidentate iminopyridine ligands: Synthesis, spectral characterization, properties and structural analysis" @default.
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- W2012317215 doi "https://doi.org/10.1016/j.poly.2010.04.015" @default.
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