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• W2012324558 abstract "Abstract The model set forth in Part I for analyzing the elementary chemical step (ECS) in the case of solid state reactions is applied to an examination of the thermal decomposition, photolysis, and radiolysis of metal azides. A comparison is made of various possible elementary chemical transformations of the structural units (SU) of the crystals of these salts. At the same time, correlations in orbital symmetry and spin are analyzed, and correlation diagrams (CD) that identify the electronic terms of the SU and the products of their transformation are constructed. On the basis of an analysis of the ECS, the mechanism of the chemical step of decomposition of the salts tested is formulated and an interpretation is given to various experimental data (composition and yield of products, catalysis and autocatalysis, effect of magnetic field, etc.)." @default.
• W2012324558 created "2016-06-24" @default.
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• W2012324558 date "1978-10-01" @default.
• W2012324558 modified "2023-09-23" @default.
• W2012324558 title "Modeling of the elementary step of chemical transformation of crystals: II. Application to decomposition of metal azides" @default.
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• W2012324558 doi "https://doi.org/10.1016/0022-4596(78)90143-3" @default.
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