Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012330773> ?p ?o ?g. }
- W2012330773 endingPage "3444" @default.
- W2012330773 startingPage "3436" @default.
- W2012330773 abstract "Abstract Reaction of [Rh(μ‐O t Bu)(diene)] 2 [diene = 1,5‐cyclooctadiene (COD) or bicyclo[2.2.1]hepta‐2,5‐diene (NBD)] with the oxazolinylcarbene ligand precursor 2‐(4,4‐dimethyl)oxazolinylimidazolium bromide (“Me 2 carboxH + Br − ”, 2 ) yielded the five‐coordinate complexes [RhBr(Me 2 carbox)(diene)] [diene = COD ( 3 ), NBD ( 4 )]. Single‐crystal X‐ray structure analyses established a distorted trigonal bipyramidal configuration for 3 , whereas the molecular structure of 4 is distorted square pyramidal. The dynamic properties of these five‐coordinate complexes have been investigated by variable temperature 1 H NMR spectroscopy, indicating polytopal rearrangements of the five‐coordinate complexes. The two compounds were converted into the square‐planar cationic complexes [Rh(Me 2 carbox)(diene)] + ( 5 and 6 , respectively), which have been isolated and fully characterised. The rhodium complex [RhBr(Me 2 carbox)(CO)] ( 7 ) was obtained in high yield in a one‐step reaction of the ligand precursor 2 and [Rh(acac)(CO) 2 ] (acac = acetylacetonate). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
- W2012330773 created "2016-06-24" @default.
- W2012330773 creator A5030004931 @default.
- W2012330773 creator A5066055309 @default.
- W2012330773 creator A5071786606 @default.
- W2012330773 date "2004-08-23" @default.
- W2012330773 modified "2023-10-18" @default.
- W2012330773 title "Cationic and Neutral Rhodium(<scp>I</scp>) Oxazolinylcarbene Complexes" @default.
- W2012330773 cites W144833344 @default.
- W2012330773 cites W1834214563 @default.
- W2012330773 cites W1940109774 @default.
- W2012330773 cites W1969188989 @default.
- W2012330773 cites W1969936568 @default.
- W2012330773 cites W1976745590 @default.
- W2012330773 cites W1992899849 @default.
- W2012330773 cites W1993269746 @default.
- W2012330773 cites W2000855413 @default.
- W2012330773 cites W2000899806 @default.
- W2012330773 cites W2001461847 @default.
- W2012330773 cites W2002374188 @default.
- W2012330773 cites W2005009375 @default.
- W2012330773 cites W2025603208 @default.
- W2012330773 cites W2032116402 @default.
- W2012330773 cites W2043988170 @default.
- W2012330773 cites W2045666877 @default.
- W2012330773 cites W2046764048 @default.
- W2012330773 cites W2050873427 @default.
- W2012330773 cites W2053349074 @default.
- W2012330773 cites W2055579540 @default.
- W2012330773 cites W2058767980 @default.
- W2012330773 cites W2060518866 @default.
- W2012330773 cites W2064554391 @default.
- W2012330773 cites W2065948329 @default.
- W2012330773 cites W2081069571 @default.
- W2012330773 cites W2082497708 @default.
- W2012330773 cites W2084199856 @default.
- W2012330773 cites W2094160044 @default.
- W2012330773 cites W2096397973 @default.
- W2012330773 cites W2101647682 @default.
- W2012330773 cites W2104057453 @default.
- W2012330773 cites W2113348154 @default.
- W2012330773 cites W2142809411 @default.
- W2012330773 cites W2144085609 @default.
- W2012330773 cites W2149028025 @default.
- W2012330773 cites W2166291607 @default.
- W2012330773 cites W4211172071 @default.
- W2012330773 doi "https://doi.org/10.1002/ejic.200400182" @default.
- W2012330773 hasPublicationYear "2004" @default.
- W2012330773 type Work @default.
- W2012330773 sameAs 2012330773 @default.
- W2012330773 citedByCount "43" @default.
- W2012330773 countsByYear W20123307732012 @default.
- W2012330773 countsByYear W20123307732013 @default.
- W2012330773 countsByYear W20123307732014 @default.
- W2012330773 countsByYear W20123307732015 @default.
- W2012330773 countsByYear W20123307732016 @default.
- W2012330773 countsByYear W20123307732017 @default.
- W2012330773 countsByYear W20123307732018 @default.
- W2012330773 countsByYear W20123307732020 @default.
- W2012330773 countsByYear W20123307732023 @default.
- W2012330773 crossrefType "journal-article" @default.
- W2012330773 hasAuthorship W2012330773A5030004931 @default.
- W2012330773 hasAuthorship W2012330773A5066055309 @default.
- W2012330773 hasAuthorship W2012330773A5071786606 @default.
- W2012330773 hasConcept C111592845 @default.
- W2012330773 hasConcept C115624301 @default.
- W2012330773 hasConcept C116569031 @default.
- W2012330773 hasConcept C155647269 @default.
- W2012330773 hasConcept C161790260 @default.
- W2012330773 hasConcept C168382676 @default.
- W2012330773 hasConcept C170493617 @default.
- W2012330773 hasConcept C176933379 @default.
- W2012330773 hasConcept C178790620 @default.
- W2012330773 hasConcept C183882617 @default.
- W2012330773 hasConcept C185592680 @default.
- W2012330773 hasConcept C188027245 @default.
- W2012330773 hasConcept C2776300020 @default.
- W2012330773 hasConcept C2778733088 @default.
- W2012330773 hasConcept C2779910884 @default.
- W2012330773 hasConcept C512735826 @default.
- W2012330773 hasConcept C521398313 @default.
- W2012330773 hasConcept C55493867 @default.
- W2012330773 hasConcept C71240020 @default.
- W2012330773 hasConcept C8010536 @default.
- W2012330773 hasConcept C92840921 @default.
- W2012330773 hasConceptScore W2012330773C111592845 @default.
- W2012330773 hasConceptScore W2012330773C115624301 @default.
- W2012330773 hasConceptScore W2012330773C116569031 @default.
- W2012330773 hasConceptScore W2012330773C155647269 @default.
- W2012330773 hasConceptScore W2012330773C161790260 @default.
- W2012330773 hasConceptScore W2012330773C168382676 @default.
- W2012330773 hasConceptScore W2012330773C170493617 @default.
- W2012330773 hasConceptScore W2012330773C176933379 @default.
- W2012330773 hasConceptScore W2012330773C178790620 @default.
- W2012330773 hasConceptScore W2012330773C183882617 @default.
- W2012330773 hasConceptScore W2012330773C185592680 @default.
- W2012330773 hasConceptScore W2012330773C188027245 @default.
- W2012330773 hasConceptScore W2012330773C2776300020 @default.