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- W2012339369 abstract "Inverse gas chromatography (IGC) was applied to amphiphilic graft copolymers of poly(2-hydroxyethyl methacrylate) (PHEMA) with polystyrene (PSt) branches using various probes at 160°C. Retention of tetradecane or amylbenzene, which selectively interacts only with PSt phase, suggested that a microphase inversion occurs around 20—30 wt% PSt, below which PSt segments constitute a discontinuous phase (islands). Rather nonselective probes such as dimethyl-formamide and 2-(2-methoxyethoxy)ethanol showed a retention which exceeds that expected from a simple additive relation, suggesting a considerable contribution of their interaction with the interface of the microphase-separated domains. In contrast, random copolymers showed a retention behavior as expected for a statistical distribution of the monomer units. General discussion is given on IGC as a means of characterizing binary polymer systems." @default.
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- W2012339369 date "1983-08-01" @default.
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- W2012339369 title "Inverse Gas Chromatography on Graft and Random Copolymers of Styrene and 2-Hydroxyethyl Methacrylate" @default.
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- W2012339369 doi "https://doi.org/10.1295/polymj.15.577" @default.
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