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- W2012340505 abstract "Abstract The interstitial D sites in the D-doped A-15 compound Ti3IrDx with x = 0.70 and 3.63 were determined by neutron diffraction (space group Pm 3 n (No. 223)). For x = 0.70, we confirm the D occupation of sixfold d positions (6d positions) already found for other H- and D-doped A-15 compounds. The complete and sole occupation of these positions yields the concentration x = 3. Accordingly, we found for the sample with x = 3.63 the additional occupation of 24k (or nearly 24k) positions. Our study suggests in particular a structural mechanism that successively replaces 6d positions by two adjacent and simultaneously occupied 24k positions in order to allow an increase of the D concentration above x = 3." @default.
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- W2012340505 date "1997-02-01" @default.
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- W2012340505 title "A neutron diffraction study of the interstitial sites of deuterium in the A-15 compound Ti3Ir" @default.
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