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- W2012343446 abstract "The essential reactions catalyzed by the pyridoxal phosphate enzymes are interpreted quantum-mechanically with the help of the molecular orbital method. This method has been used for the calculation of the energy levels and the electronic distribution in pyridoxal phosphate and in the different types of the Schiff's bases, which result from the combination of pyridoxal phosphate with an α-amino acid and the subsequent labilization of different groups of this acid. The essential factors responsible for the mechanism of the reactions catalyzed by pyridoxal phosphate seem to be the variations of resonance energy associated with the formation of transitional Schiff's bases and the electronic distribution in these transitional forms." @default.
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- W2012343446 date "1961-01-01" @default.
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- W2012343446 title "Electronic aspects of the reactions of pyridoxal phosphate enzymes" @default.
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- W2012343446 doi "https://doi.org/10.1016/0006-3002(61)90586-8" @default.
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