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- W2012350822 abstract "An acid-catalyzed [4+3] cycloaddition reaction of N-nosyl pyrroles with 2-(tert-butyldimethylsilyloxy)acrolein has been developed. The reaction of 2-(silyloxy)acrolein with N-nosyl pyrrole was catalyzed by Tf2NH, and a regio- and stereoselective reaction with 2-substituted N-nosyl pyrroles leading to tropinone derivatives possessing tetra-substituted carbon centers was also achieved. High regioselectivities were obtained by using Cu(OTf)2 or Sc(OTf)3 as a catalyst in nitromethane, and the reaction was applicable to various 2-substituted N-nosyl pyrroles in good yields and with high regioselectivities." @default.
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- W2012350822 date "2015-07-01" @default.
- W2012350822 modified "2023-10-10" @default.
- W2012350822 title "Acid-catalyzed [4+3] cycloaddition reaction of N-nosyl pyrroles" @default.
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- W2012350822 doi "https://doi.org/10.1016/j.tet.2015.02.071" @default.
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