Matches in SemOpenAlex for { <https://semopenalex.org/work/W2012359518> ?p ?o ?g. }
- W2012359518 endingPage "8261" @default.
- W2012359518 startingPage "8256" @default.
- W2012359518 abstract "The nanophase separation behavior of two semi-fluorinated isophthalic acid derivatives, F8H10-ISA and F12H11-ISA, at the liquid−solid interface is studied by in situ scanning tunneling microscopy. Two polymorphs of F8H10-ISA were observed at the interface. One polymorph, which is not stable in time, showed nanosegregation of the perfluorinated segments of the alkyl chains, while the second polymorph showed a completely interdigitating lamellar structure with solvent co-deposition. This co-deposition of solvent molecules is believed to induce extra stability in the monolayer which in turn aids the molecules in overcoming the repulsive interactions induced by the perfluorinated segment of the molecule. F12H11-ISA did not exhibit nanosegregation at the liquid−solid interface, despite the longer perfluorinated segment (increase by 4 carbon atoms) with respect to the non-fluorinated segment (increase by 1 carbon atom). Instead, clustering of the molecules into units consisting of eight molecules was observed. This is explained in terms of a compromise between opposing interactions arising from the chemical nature of the molecule. Whereas the perfluorinated−non-fluorinated segments tend to induce nanosegregation in the monolayer, the hydrogen-bonding network formed by the isophthalic acid groups in combination with solvent co-deposition tends to induce an interdigitated lamellar structure." @default.
- W2012359518 created "2016-06-24" @default.
- W2012359518 creator A5030789937 @default.
- W2012359518 creator A5056264549 @default.
- W2012359518 creator A5061164328 @default.
- W2012359518 creator A5065904906 @default.
- W2012359518 creator A5068870927 @default.
- W2012359518 creator A5072097825 @default.
- W2012359518 date "2003-08-20" @default.
- W2012359518 modified "2023-10-16" @default.
- W2012359518 title "In Situ Investigation of Dynamical Nanophase Separation" @default.
- W2012359518 cites W2002280539 @default.
- W2012359518 cites W2002741007 @default.
- W2012359518 cites W2006267303 @default.
- W2012359518 cites W2007241059 @default.
- W2012359518 cites W2011360209 @default.
- W2012359518 cites W2016147237 @default.
- W2012359518 cites W2026596709 @default.
- W2012359518 cites W2029493564 @default.
- W2012359518 cites W2036150237 @default.
- W2012359518 cites W2036336213 @default.
- W2012359518 cites W2036591553 @default.
- W2012359518 cites W2037935332 @default.
- W2012359518 cites W2046225954 @default.
- W2012359518 cites W2052735997 @default.
- W2012359518 cites W2052798723 @default.
- W2012359518 cites W2062136489 @default.
- W2012359518 cites W2063632328 @default.
- W2012359518 cites W2065536386 @default.
- W2012359518 cites W2078129783 @default.
- W2012359518 cites W2084310066 @default.
- W2012359518 cites W2084720720 @default.
- W2012359518 cites W2085912173 @default.
- W2012359518 cites W2086812728 @default.
- W2012359518 cites W2089334898 @default.
- W2012359518 cites W2092242276 @default.
- W2012359518 cites W2094046956 @default.
- W2012359518 cites W2095392143 @default.
- W2012359518 cites W2129320735 @default.
- W2012359518 cites W2134819724 @default.
- W2012359518 cites W2160431999 @default.
- W2012359518 cites W2162417768 @default.
- W2012359518 doi "https://doi.org/10.1021/la034535s" @default.
- W2012359518 hasPublicationYear "2003" @default.
- W2012359518 type Work @default.
- W2012359518 sameAs 2012359518 @default.
- W2012359518 citedByCount "9" @default.
- W2012359518 countsByYear W20123595182014 @default.
- W2012359518 countsByYear W20123595182017 @default.
- W2012359518 countsByYear W20123595182023 @default.
- W2012359518 crossrefType "journal-article" @default.
- W2012359518 hasAuthorship W2012359518A5030789937 @default.
- W2012359518 hasAuthorship W2012359518A5056264549 @default.
- W2012359518 hasAuthorship W2012359518A5061164328 @default.
- W2012359518 hasAuthorship W2012359518A5065904906 @default.
- W2012359518 hasAuthorship W2012359518A5068870927 @default.
- W2012359518 hasAuthorship W2012359518A5072097825 @default.
- W2012359518 hasConcept C104779481 @default.
- W2012359518 hasConcept C119394753 @default.
- W2012359518 hasConcept C127413603 @default.
- W2012359518 hasConcept C140205800 @default.
- W2012359518 hasConcept C159985019 @default.
- W2012359518 hasConcept C171250308 @default.
- W2012359518 hasConcept C178790620 @default.
- W2012359518 hasConcept C185592680 @default.
- W2012359518 hasConcept C192562407 @default.
- W2012359518 hasConcept C2779271837 @default.
- W2012359518 hasConcept C2780263894 @default.
- W2012359518 hasConcept C2780330708 @default.
- W2012359518 hasConcept C2780471494 @default.
- W2012359518 hasConcept C32909587 @default.
- W2012359518 hasConcept C42360764 @default.
- W2012359518 hasConcept C6518042 @default.
- W2012359518 hasConcept C7070889 @default.
- W2012359518 hasConcept C77851909 @default.
- W2012359518 hasConcept C8010536 @default.
- W2012359518 hasConceptScore W2012359518C104779481 @default.
- W2012359518 hasConceptScore W2012359518C119394753 @default.
- W2012359518 hasConceptScore W2012359518C127413603 @default.
- W2012359518 hasConceptScore W2012359518C140205800 @default.
- W2012359518 hasConceptScore W2012359518C159985019 @default.
- W2012359518 hasConceptScore W2012359518C171250308 @default.
- W2012359518 hasConceptScore W2012359518C178790620 @default.
- W2012359518 hasConceptScore W2012359518C185592680 @default.
- W2012359518 hasConceptScore W2012359518C192562407 @default.
- W2012359518 hasConceptScore W2012359518C2779271837 @default.
- W2012359518 hasConceptScore W2012359518C2780263894 @default.
- W2012359518 hasConceptScore W2012359518C2780330708 @default.
- W2012359518 hasConceptScore W2012359518C2780471494 @default.
- W2012359518 hasConceptScore W2012359518C32909587 @default.
- W2012359518 hasConceptScore W2012359518C42360764 @default.
- W2012359518 hasConceptScore W2012359518C6518042 @default.
- W2012359518 hasConceptScore W2012359518C7070889 @default.
- W2012359518 hasConceptScore W2012359518C77851909 @default.
- W2012359518 hasConceptScore W2012359518C8010536 @default.
- W2012359518 hasIssue "20" @default.
- W2012359518 hasLocation W20123595181 @default.
- W2012359518 hasOpenAccess W2012359518 @default.