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- W2012364998 abstract "Under the influence of an Ir(I) metal fragment, the methyl group of phenyl(methyl)ketene undergoes two C-H activations in reacting with internal alkynes, giving metallacycles 3 in 86-94% yield. Treatment of 3 with CO liberates 1,4-dien-3-ones 5 in 81-93% yield, along with CO complex 4. A possible mechanism for the very selective double C-H activation-alkyne coupling is discussed." @default.
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- W2012364998 date "2004-07-01" @default.
- W2012364998 modified "2023-10-17" @default.
- W2012364998 title "Double C−H Activation during Functionalization of Phenyl(methyl)ketene on Iridium(I) Using Alkynes. Synthesis of 1,4-Dien-3-ones" @default.
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- W2012364998 doi "https://doi.org/10.1021/ja048489+" @default.
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