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• W2012371560 abstract "Novel ternary ytterbium-zinc-silicides and germanides have been synthesized using pure zinc metal as a flux-solvent. The new compounds, YbZn2Si2 and YbZn2Ge2 crystallize with the BaAl4 or ThCr2Si2-type. Yb(Zn,Si)2 and Yb(Zn,Si)2−x crystallize with the ThSi2 and the GdSi2−x type, respectively. Crystal properties were characterized using X-ray single crystal analysis via Gandolfi and Weissenberg film techniques, by flat specimen X-ray powder diffractometry and in some cases by automatic four circle X-ray single crystal diffractometry. Depending on the heating and cooling program in the synthesis, various lattice parameter values were obtained suggesting the existence of homogeneity regions. Both the Yb-Zn-silicides and the germanide show a temperature independent Pauli-type paramagnetic behaviour down to liquid He temperature consistent with the XAS-measurements revealing an Yb2+ ground state." @default.
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• W2012371560 date "1998-02-01" @default.
• W2012371560 modified "2023-09-30" @default.
• W2012371560 title "Novel ytterbium-zinc-silicides and germanides grown from zinc-flux" @default.
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• W2012371560 doi "https://doi.org/10.1016/s0925-8388(97)00455-6" @default.
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