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- W2012384688 abstract "Abstract The effect of stoichiometric replacement of Pb and Bi by vanadium in the Bi-based systems has been studied. In a series of samples with nominal composition BiaPbbVcSr4Ca5Cu7Ox(a + b + c = 4) the influence of the dopant was detected by measurement of the electrical resistivity, critical current density and magnetic susceptibility, by x-ray analysis and by SEM with an x-ray electron microprobe. The sample with substitution ofV for Bi and with content of Pb,b = 0.8, showed the highest content of the 2223 phase and improved intergrain boundaries. An increasing substitution of V for Pb got worse superconducting properties. In the samples with the composition Bi2.6Pb0.8V0.6Sr4Ca5Cu7Oxsintered for different time periods, vanadium was found in the form of various double oxides, mainly as Sr3V2O8. A certain amount of vanadium was detected in the 2223 phase by the Electron Microprobe, but it probably was some finely dispersed phase with a grain size below the resolution of our SEM." @default.
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- W2012384688 date "1997-04-01" @default.
- W2012384688 modified "2023-10-17" @default.
- W2012384688 title "Vanadium substituted Bi–Pb–Sr–Cu–O superconductors" @default.
- W2012384688 doi "https://doi.org/10.1006/spmi.1996.0406" @default.
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