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- W2012387589 abstract "Two novel Cd(II) coordination frameworks based on a semirigid asymmetric ligand L and aromatic multi-carboxylate ligands, {[Cd2L(btc)(H2O)2]·5H2O}n (1) and [Cd2L2(bdc)]n (2) (L = (4-((2-(pyridine-2-yl)-1H-imidazol-1-yl)methyl)benzoic acid, H3btc = 1,3,5-benzenetricarboxylic acid, H2bdc = 1,3-benzenedicarboxylic acid), have been hydrothermally synthesized, and structurally characterized by elemental analysis, IR spectroscopy, single-crystal X-ray crystallography. Due to various coordination modes and conformations of the semirigid asymmetric ligand, and carboxylate containing co-ligands, therefore, the two complexes exhibit structural and dimensional diversity. Complex 1 exhibits a novel 2D (3, 5)-connected network structure with (3·52)(32·53·64·7) topology. Complex 2 exhibits a novel 3D CdSO4 topology, which is formed from different dinuclear cadmium units. In addition, the photoluminescence properties of the free ligand L, and complexes 1 and 2 were studied in the solid state at room temperature." @default.
- W2012387589 created "2016-06-24" @default.
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- W2012387589 date "2009-09-01" @default.
- W2012387589 modified "2023-10-17" @default.
- W2012387589 title "Syntheses, structures, and photoluminescence of two Cd(II) coordination polymers constructed from analogue (pyridyl)imidazole derivative and polycarboxylate acid" @default.
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- W2012387589 doi "https://doi.org/10.1016/j.inoche.2009.07.013" @default.
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