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• W2012393182 abstract "CuGaSe2 (CGS) crystals (Cu/Ga=0.9–1.4) which have been expected as photovoltaic applications were successfully grown by a vertical gradient freezing method. All samples were of the chalcopyrite structures, nearly stoichiometric and showed p-type conductivities. The samples became poor crystallinity with increasing enclosed Cu/Ga ratios in the Cu-rich region because the values of full-width at half-maximum at (1 1 2) diffraction lines increased with increasing enclosed Cu/Ga ratios. Lattice constants of a and c axes in the Cu-rich regions were larger than those in the Cu-poor regions, indicating that Cu atoms played an important role with the lattice constants. The grown stoichiometric CGS sample was of high quality since the free-exciton emission line was clearly observed in photoluminescence (PL) spectrum at 77 K. The CGS samples turned out to have many donor- and acceptor-type defects because the donor–acceptor pair emission bands had considerable intensities in the PL spectra." @default.
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• W2012393182 date "2001-01-01" @default.
• W2012393182 modified "2023-10-14" @default.
• W2012393182 title "Photoluminescence spectra of CuGaSe2 crystals" @default.
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• W2012393182 doi "https://doi.org/10.1016/s0921-4526(01)00454-9" @default.
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