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- W2012409545 abstract "The dynamic nuclear quadrupole interaction (first derivative of the quadrupole interaction with respect to strain) has been measured for the I127 nucleus in crystals of CsI, RbI, KI, and NaI. These measurements were made by observing the resonant absorption of energy from an acoustic wave by the nuclear spins. Longitudinal waves propagating along a cubic axis of the crysta were used. The observed values of the dynamic nuclear quadrupole interaction are: CsI, 1600 Mc; RbI, 615 Mc; KI, 300 Mc; NaI, 660 Mc. These values can be correlated with the chemical shift of the iodine ion in these crystals with the help of a simple model. This model, which is based on work of Townes and Dailey and Yosida and Moriya, attributes the quadrupole coupling and the chemical shift to the hole left in the outer p shell of the ion. This hole is due to the distortion of the ion (admixture of excited states) by the crystal surroundings. In connection with this work, the chemical shift of LiI127 was measured and found to be −3.3×10−4." @default.
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- W2012409545 date "1961-04-01" @default.
- W2012409545 modified "2023-10-18" @default.
- W2012409545 title "Nuclear quadrupole coupling in alkali iodide crystals" @default.
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- W2012409545 doi "https://doi.org/10.1016/0022-3697(61)90060-9" @default.
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