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- W2012409905 abstract "Abstract The complexes [Ru{(Z)-HC CHPh}(CO)2(η5-C5Ph5)] (1) and [Ru{(Z)-HC CHC6H4NO2}(CO)2(η5-C5Ph5)] (2) have been synthesized and their identity confirmed by single-crystal X-ray diffraction studies. Reaction of 2 with PMe2Ph and Me3NO in tetrahydrofuran afforded [Ru{(Z)-HC CHC6H4NO2}(CO)(PMe2Ph)(η5-C5Ph5)] (3). Cyclic voltammetry confirms the expected increase in ease of oxidation on proceeding from 2 to 1 and from 2 to 3. Hyper-Rayleigh scattering studies at 1064 nm reveal a dramatic increase in quadratic non-linearity on co-ligand replacement of CO by PMe2Ph, in proceeding from 2 to 3. Z-scan studies at 800 nm are consistent with significant contribution from two-photon states, and with an increase in γreal on co-ligand replacement of CO by PMe2Ph in proceeding from 2 to 3." @default.
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- W2012409905 date "2005-03-01" @default.
- W2012409905 modified "2023-09-28" @default.
- W2012409905 title "Synthesis and non-linear optical properties of (η5-pentaphenylcyclopentadienyl)dicarbonylruthenium(II) σ-alkenyl complexes" @default.
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- W2012409905 doi "https://doi.org/10.1016/j.ica.2004.09.045" @default.
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