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• W2012431990 abstract "2,4,6-Tri-tert-butylphenolate and 2,6-di-tert-butyl-4-methoxyphenolate (prepared by reacting the corresponding phenols with dry Et4NOH) were oxidised by one-electron in CH3CN at room temperature (with 0.2 M Bu4NPF6 as the supporting electrolyte) in a controlled potential electrolysis cell at negative potentials (−0.68 to −0.84 V vs. Fc/Fc+ (Fc=ferrocene)) to produce moderately stable phenoxyl radicals. The oxidation reaction was monitored using in situ FTIR spectroscopy between 1800–1000 cm−1 with an attenuated total reflectance (ATR) probe containing a diamond composite sensor inserted into the working electrode compartment of the electrolysis cell. Analysis of the data obtained during the chemically reversible oxidation of the phenolate anions allowed the identification of several IR absorption bands that could be assigned to the phenoxyl radicals with notable bands observed at 1592–1573 cm−1 and 1505–1509 cm−1 that were assigned to the ν8a(CoCm ring stretch) and ν7a(Ca–O stretch) modes, respectively." @default.
• W2012431990 created "2016-06-24" @default.
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• W2012431990 date "2003-01-01" @default.
• W2012431990 modified "2023-10-11" @default.
• W2012431990 title "In situ electrochemical-ATR-FTIR spectroscopic studies on solution phase 2,4,6-tri-substituted phenoxyl radicals" @default.
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• W2012431990 doi "https://doi.org/10.1016/s1388-2481(02)00517-9" @default.
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