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- W2012437047 abstract "The crystal structures of (ND4)2[Cu(D2O)6](SO4)2 at 295 K, determined by X-ray diffraction at pressures of 1 bar, ∼1.5 kbar and ∼3.0 kbar, are reported. Between 1 bar and 1.5 kbar, the crystal structure changes to one almost identical to that of the corresponding hydrogenous compound at 1 bar. The structural change involves a 90° switch in the direction of the long bonds of the Cu(D2O)62+ ion, accompanied by a change in the hydrogen-bonding interactions of the ammonium cations. Comparison of these two structures with those at ∼15 K shows that at room temperature, for both the high (H) and low (L) pressure phases, the Cu complexes are in thermal equilibrium with the other structural isomer. Though one of these is energetically preferred in the H and the other in the L phase, the variation of the powder EPR spectrum with pressure indicates a continuous transition between both within ∼1 kbar and suggests that at ∼0.5 kbar the two orientations of the copper complex are similar in energy. However, the underlyi..." @default.
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- W2012437047 date "1996-01-01" @default.
- W2012437047 modified "2023-10-16" @default.
- W2012437047 title "Pressure Dependence of the Crystal Structures and EPR Spectra of Potassium Hexaaquacopper(II) Sulfate and Deuterated Ammonium Hexaaquacopper(II) Sulfate" @default.
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- W2012437047 doi "https://doi.org/10.1021/ic950857a" @default.
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