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• W2012461021 abstract "The tripodal N,N,O ligands 3,3-bis(3,5-dimethylpyrazol-1-yl)propionic acid (Hbdmpzp) (1) and 3,3-bis(pyrazol-1-yl)propionic acid (Hbpzp) (2) form the “missing link” between the well-known bis(pyrazol-1-yl)acetic acids and related ligands with a longer “carboxylate arm”. To illustrate the reactivity of this ligand, manganese and rhenium complexes bearing the ligand bdmpzp are reported. The complexes are compared to related compounds bearing other tripod ligands such as bis(3,5-dimethylpyrazol-1-yl)acetate (bdmpza) and 3,3-bis(1-methylimidazol-2-yl)propionate (bmip). Spectroscopic and structural data are used as a basis for comparison, as well as DFT calculations. Both ligands 1 and 2 and the complexes fac-[Mn(bdmpzp)(CO)3] (3) and fac-[Re(bdmpzp)(CO)3] (4) were characterised by X-ray crystallography." @default.
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• W2012461021 date "2009-07-01" @default.
• W2012461021 modified "2023-10-18" @default.
• W2012461021 title "3,3-Bis(3,5-dimethylpyrazol-1-yl)propionic acid: A tripodal N,N,O ligand for manganese and rhenium complexes – Syntheses and structures" @default.
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• W2012461021 doi "https://doi.org/10.1016/j.jorganchem.2009.03.037" @default.
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