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- W2012476263 abstract "We have investigated the linear--electric-field effect (LEFE) in cupric ions situated in ligand fields of low symmetry. General properties of LEFE signals resulting from various low-symmetry models are described. Treating g values, we show how hybrid-orbital ``united-atom'' models can be used for direct calculation of the LEFE signal expected from cupric sites of specific low-symmetry geometries. This hybrid--atomic-orbital approach is shown to give a straightforward method for interpreting LEFE data in terms of cupric electronic states that directly reflect the ligand environment. Results are presented which demonstrate the potential of calculations with this model to account quantitatively for the LEFE data from blue cupric proteins." @default.
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- W2012476263 date "1988-03-01" @default.
- W2012476263 modified "2023-09-26" @default.
- W2012476263 title "Linear<i>–</i>electric-field effect on<i>g</i>values of low-symmetry cupric sites" @default.
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- W2012476263 doi "https://doi.org/10.1103/physreva.37.2151" @default.
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