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- W2012485660 abstract "Relative rates of consumption of caffeic, ferulic and sinapic acids by 2,2′-azobis(2-amidine propane) derived peroxyl radicals has been measured in parallel experiments employing a single substrate and in competitive experiments. Rates of consumption measured in independent experiments at low substrate concentrations (first order limit) follow the order: sinapic > ferulic > caffeic. In agreement with this, in competitive experiments employing simultaneously sinapic and caffeic acid the former compound is consumed considerably faster. On the other hand, in competitive experiments employing ferulic and caffeic acids over a wide range of experimental conditions, caffeic acid is consumed considerably faster than ferulic acid, a result that contrasts with that obtained when both compounds are reacted independently. These apparently anomalous results are interpreted in terms of secondary reactions of the phenol-derived radicals. In particular, hydrogen transfer among phenoxyl radicals and the phenols and fast r..." @default.
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- W2012485660 date "2007-01-01" @default.
- W2012485660 modified "2023-10-17" @default.
- W2012485660 title "Competitive kinetics in free radical reactions of cinnamic acid derivatives. Influence of phenoxyl radicals reactions" @default.
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- W2012485660 doi "https://doi.org/10.1080/10715760701583969" @default.
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