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• W2012488270 startingPage "1225" @default.
• W2012488270 abstract "Enantiomerically pure (S)-mandelic acid was synthesised from benzaldehyde by sequential hydrocyanation and hydrolysis in a bienzymatic cascade at starting concentrations up to 0.25 M. A cross-linked enzyme aggregate (CLEA) composed of the (S)-selective oxynitrilase from Manihot esculenta and the non-selective nitrilase from Pseudomonas fluorescens EBC 191 was employed as the biocatalyst. The nitrilase produces approx. equal amounts of (S)-mandelic acid and (S)-mandelic amide from (S)-mandelonitrile under standard conditions, but we surprisingly found that high (up to 0.5 M) concentrations of HCN induced a marked drift towards amide production. By including the amidase from Rhodococcus erythopolis in the CLEA we obtained (S)-mandelic acid as the sole product in 90% yield and >99% enantiomeric purity." @default.
• W2012488270 created "2016-06-24" @default.
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• W2012488270 date "2013-10-01" @default.
• W2012488270 modified "2023-09-26" @default.
• W2012488270 title "The combi-CLEA approach: enzymatic cascade synthesis of enantiomerically pure (S)-mandelic acid" @default.
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• W2012488270 doi "https://doi.org/10.1016/j.tetasy.2013.08.013" @default.
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