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- W2012492104 abstract "The primordial influence of the silyl group in an intramolecular thermal H-ene reaction is reported. The silyl group lowered the energy of the transition state and allowed the reaction to proceed at a lower temperature than that of the simple all-carbon analog, thereby excluding the formation of undesirable by-products. This sequence has been applied for new access to a key intermediate in the diastereoselective synthesis of (±)-cis-γ-irone with high chemocontrol and significantly improved overall yield." @default.
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- W2012492104 date "1999-08-01" @default.
- W2012492104 modified "2023-09-27" @default.
- W2012492104 title "Silicon-Controlled Intramolecular Thermal H-Ene Reaction – A New Access to a Key Intermediate of (±)-cis-γ-Irone" @default.
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- W2012492104 doi "https://doi.org/10.1002/(sici)1099-0690(199908)1999:8<1825::aid-ejoc1825>3.0.co;2-5" @default.
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