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• W2012502068 endingPage "568" @default.
• W2012502068 startingPage "558" @default.
• W2012502068 abstract "The calculations of Flory and co-workers for the formation and composition of isotropic, bi-phasic and anisotropic systems composed of rod-like macromolecules in solution have been extended to include a Gaussian distribution of rod-lengths. The critical concentrations for the beginning and end of the bi-phasic range vo∗p and vo∗∗p respectively, the volume fraction of anisotropic phase ΦA, the compositions and average molecular weights of isotropic and anisotropic phases, and the order parameter S of the anisotropic phase are calculated as a function of polymer concentration vop for rod-length xo in the range 30 to 70 and for a Gaussian distribution half-width Δ12 in the range 10 to 70. The extent of the bi-phasic range and the composition of the two components is found to be strongly dependent on the breadth of the distribution and average rod-length. The applicability of the calculations to data for poly(alkylisocyanates) in solution is briefly considered." @default.
• W2012502068 created "2016-06-24" @default.
• W2012502068 creator A5068093694 @default.
• W2012502068 creator A5076025635 @default.
• W2012502068 date "1982-04-01" @default.
• W2012502068 modified "2023-09-26" @default.
• W2012502068 title "The effect of a Gaussian distribution of chain-lengths on the phase-behaviour of a model system of rod-like macromolecules in solution" @default.
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• W2012502068 doi "https://doi.org/10.1016/0032-3861(82)90095-7" @default.
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